Napoli beat Eintracht Frankfurt 3-0 on Wednesday to reach the Champions League quarter-finals for the first time in its history.
Inter Milan reached the Champions League quarter-finals for the first time in more than a decade after a 0-0 draw with Porto, which took them through 1-0 on aggregate.
Erling Haaland scored five goals to power Manchester City into the quarter-finals of the Champions League with a 7-0 win over RB Leipzig at the Etihad Stadium.
Liverpool exited the Champions League with a 6-2 aggregate defeat to Real Madrid as Karim Benzema's late strike condemned the Reds to a 1-0 loss in the second leg.
Karim Adeyemi’s goal for Borussia Dortmund means Chelsea have a 1-0 deficit to overcome following the first leg of their Champions League round of 16 tie.
Joao Mario's second-half penalty and a late goal from David Neres saw Benfica win 2-0 away over Club Brugge in the first leg of their Champions League last-16 tie.
Kingsley Coman returned to haunt Paris Saint-Germain again as he earned Bayern Munich a 1-0 win at the Parc des Princes.
Brahim Diaz's early goal condemned Tottenham to a 1-0 loss against AC Milan in the first leg of their Champions League last-16 tie at San Siro.
All four English teams qualified for the Champions League last 16 but both Scottish sides exited the competition at the group stage.
Paris Saint-Germain were forced to settle for second in their Champions League group after a dramatic conclusion saw Benfica pip them by virtue of away goals scored.
Ben Chilwell's injury is a concern with less than three weeks until England's World Cup campaign begins, says Chelsea head coach Graham Potter.
Raheem Sterling was restored to Chelsea's attack and rewarded Graham Potter with a starring role in a 2-1 win over Dinamo Zagreb which saw Ben Chilwell limp off late on.
Rico Lewis became the youngest player to score on his first Champions League start as he sparked a Manchester City comeback in a 3-1 win over Sevilla.
Celtic finished their Champions League campaign winless after being thrashed 5-1 at holders Real Madrid, who qualified for the last 16 as Group F winners.
Tottenham will play in the last 16 of the Champions League after Pierre-Emile Hojbjerg's strike in stoppage time snatched a dramatic 2-1 win at Marseille.
Rangers recorded the worst campaign in Champions League history as they lost 3-1 to Ajax in their final group match.
Late goals from Mohamed Salah and Darwin Nunez helped Liverpool to a 2-0 win over Napoli but the Italians still finished top dogs in Champions League Group A.
With all four English teams guaranteed Champions League knockout spots, when is the draw for the last 16 and who will be involved?
Giovanni Simeone's impressive double and a late Leo Ostigard header secured Napoli a convincing 3-0 victory in Naples.
Harry Kane was denied a dramatic last-minute winner by VAR against Sporting Lisbon that would have sent Tottenham into the last 16 of the Champions League.