Shkodran Mustafi, Moussa Sissoko and Paco Alcacer will all be on international duty over the next week, and you can watch them - live on Sky Sports.
Spain, Germany, France and Portugal all feature between Friday and Tuesday, as attention turns to qualification for the 2018 World Cup.
We have picked out five new signings who will be in action on Sky Sports…
Shkodran Mustafi (Arsenal) - Norway v Germany, live on Sky Sports 3, Sunday
Arsenal's new No 20 played 90 minutes in Germany's 2-0 win over Finland on Wednesday and is in contention for another cap when Joachim Low's side face Norway on Sunday.
The reigning world champions kick off their qualification campaign in Oslo with a number of injury concerns, with Kevin Volland and Emre Can ruled out and Julian Draxler recovering from flu.
Jeff Hendrick (Burnley) - Serbia v Republic of Ireland, live on Sky Sports Mix, Monday
Burnley's club-record signing starred for the Republic of Ireland at Euro 2016, and those performances in France likely stoked Sean Dyche's interest in the former Derby man.
An ever-present for Martin O'Neill in the summer, he was a second-half substitute in their friendly victory over Oman on Wednesday, but should return to the starting XI against Serbia on Monday.
Paco Alcacer (Barcelona) - Spain v Liechtenstein, live on Sky Sports Xtra, Monday
Barcelona's new striker has a 100 million euros buyout clause in his five-year contract at the Nou Camp, where he'll likely deputise for Luis Suarez.
He will be looking to stake his claim at international level, though, with Real Madrid's Alvaro Morata and Chelsea's Diego Costa his main competition for a central berth.
Hal Robson-Kanu (West Brom) - Wales v Moldova, live on Sky Sports 1, Monday
Wales forward Robson-Kanu became an overnight sensation at Euro 2016, but waited until the final moments of the window before choosing his next club.
The new West Brom man will be hoping to get back up to speed quickly having missed the first few games of the season, but could get the chance for minutes when Chris Coleman's side open their World Cup campaign at home to minnows Moldova.
Moussa Sissoko (Tottenham) - Belarus v France, live on Sky Sports 2, Tuesday
Sissoko was a stand-out for France as the host nation reached the Euro 2016 final, and Tottenham fans will want more of the same when he turns up at White Hart Lane.
First up, though, the £30m midfielder takes on Belarus as Didier Deschamps' side begin their quest for World Cup qualification.