Joshua Buatsi, Lawrence Okolie, Joe Cordina and Conor Benn will fight at York Hall on September 1 on the latest NXTGEN show.
The three unbeaten Olympians will be joined by Benn, Ted Cheeseman, Felix Cash and Danny Dignum on the bill which will be aired live on Sky Sports.
Olympic bronze medallist Buatsi made his debut in style at The O2 earlier this month, and the Croydon fighter will be hoping to put on another impressive display in London.
Okolie and Cordina started life in the paid ranks slightly earlier than Buatsi and both have so far stopped all their opponents in the scheduled distance.
The card will also feature four of Cordina's gym-mates as hard-hitting Benn continues his comeback from injury, while Cheeseman boxes fresh from his English super-welterweight title victory.
Unbeaten duo Felix Cash and Danny Dignum will also be in action with the full card to be announced over the coming days.